Resonance Chemistry Basic Inorganic Nomeclature
Here's a simplified and structured guide to help you understand the topic:
Contents
🧪 Resonance Chemistry: Basic Inorganic Nomenclature
📌 1. What is Resonance in Chemistry?
Resonance is a concept used to describe the delocalization of electrons in molecules where a single Lewis structure is not enough to represent the bonding.
🧬 Definition:
Resonance occurs when two or more valid Lewis structures can be drawn for the same molecule, and the actual structure is a hybrid of these forms.
✅ Example:
Ozone (O₃)
It has two resonance structures:
O=O–O ↔ O–O=O
But the actual structure is a resonance hybrid, where both O–O bonds are of equal length.
📚 2. What is Inorganic Nomenclature?
Inorganic nomenclature is the system of naming inorganic compounds based on rules set by IUPAC (International Union of Pure and Applied Chemistry).
🧾 3. Basic Inorganic Nomenclature Rules
🔹 Binary Ionic Compounds (Metal + Non-metal):
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Name the metal first, then the non-metal with an -ide ending.
Examples:
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NaCl → Sodium chloride
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MgO → Magnesium oxide
🔹 Transition Metals (with variable charges):
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Use Roman numerals to indicate the metal's oxidation state.
Examples:
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FeCl₂ → Iron(II) chloride
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FeCl₃ → Iron(III) chloride
🔹 Polyatomic Ions:
Some ions have specific names you must memorize.
| Formula | Name |
|---|---|
| NO₃⁻ | Nitrate |
| SO₄²⁻ | Sulfate |
| OH⁻ | Hydroxide |
| NH₄⁺ | Ammonium |
Example:
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NaNO₃ → Sodium nitrate
🔹 Hydrates:
Compounds with water molecules attached.
Example:
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CuSO₄·5H₂O → Copper(II) sulfate pentahydrate
🔹 Acids:
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Hydro + base name + ic acid (for anions ending in -ide)
→ HCl → Hydrochloric acid
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-ate → -ic acid, -ite → -ous acid
→ HNO₃ (nitrate) → Nitric acid
→ HNO₂ (nitrite) → Nitrous acid
🔁 Connection Between Resonance & Nomenclature:
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Resonance affects molecular structure and stability, but not the name of the compound.
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However, understanding electron delocalization is essential for drawing correct structures and predicting compound behavior.
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