CLASSIFICATION OF ORGANIC COMPOUND – OPEN CHAIN COMPOUND – CYCLIC COMPOUND AND ITS TYPE.
CLASSIFICATION OF ORGANIC COMPOUND – OPEN CHAIN COMPOUND – CYCLIC COMPOUND AND ITS TYPE.
Here’s a clear explanation of the Classification of Organic Compounds, focusing on Open Chain Compounds and Cyclic Compounds, along with their types:
Contents [hide]
- 1
CLASSIFICATION OF ORGANIC COMPOUNDS
- 1.1
OPEN CHAIN COMPOUNDS (Acyclic Compounds)
- 1.2
CYCLIC COMPOUNDS (Closed Chain Compounds)
- 1.3
A. Homocyclic (Carbocyclic) Compounds
- 1.4
B. Heterocyclic Compounds
- 1.5
Summary Chart:
- 1.6
Tips to Remember:
- 1.7 CLASSIFICATION OF ORGANIC COMPOUND – OPEN CHAIN COMPOUND – CYCLIC COMPOUND AND ITS TYPE.
- 1.8 Organic chemistry – sOme Basic PrinciPles and Techniques
- 1.9 Nomenclature of Organic Compounds
- 1.1
CLASSIFICATION OF ORGANIC COMPOUNDS
Organic compounds are primarily classified based on the arrangement of their carbon atoms into:
OPEN CHAIN COMPOUNDS (Acyclic Compounds)
These compounds contain straight or branched chains of carbon atoms.
They do not form any rings.
Examples:
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Straight Chain:
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Methane: CH₄
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Propane: CH₃–CH₂–CH₃
-
-
Branched Chain:
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Isobutane:
CH₃–CH(CH₃)–CH₃
-
CYCLIC COMPOUNDS (Closed Chain Compounds)
These contain carbon atoms arranged in rings.
They are further classified into two major types:
A. Homocyclic (Carbocyclic) Compounds
Ring contains only carbon atoms.
➤ (i) Alicyclic Compounds
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Resemble aliphatic compounds in behavior.
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Ring of carbon atoms only, non-aromatic.
Examples:
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Cyclopropane (C₃H₆)
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Cyclobutane (C₄H₈)
➤ (ii) Aromatic Compounds
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Contain conjugated π-electrons in ring.
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Follow Hückel’s rule: (4n + 2) π electrons.
Examples:
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Benzene (C₆H₆)
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Naphthalene (C₁₀H₈)
B. Heterocyclic Compounds
Ring contains carbon atoms + other atoms (like O, N, S)
Examples:
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Furan (O in ring)
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Pyridine (N in ring)
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Thiophene (S in ring)
Summary Chart:
Type | Sub-type | Key Feature | Example |
---|---|---|---|
Open Chain | Acyclic | Straight or branched chains | Butane |
Cyclic | Alicyclic | Ring of C atoms, non-aromatic | Cyclopentane |
Aromatic | Ring with conjugated π system | Benzene | |
Heterocyclic | Ring with C + other atoms (O, N, S) | Furan, Pyridine |
Tips to Remember:
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“Alicyclic” = Aliphatic + Cyclic
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“Aromatic” = Smells + Special stability (resonance)
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“Heterocyclic” = Hetero (different) atoms in ring
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