CLASSIFICATION OF ORGANIC COMPOUND – OPEN CHAIN COMPOUND – CYCLIC COMPOUND AND ITS TYPE.

CLASSIFICATION OF ORGANIC COMPOUND – OPEN CHAIN COMPOUND – CYCLIC COMPOUND AND ITS TYPE.



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Here’s a clear explanation of the Classification of Organic Compounds, focusing on Open Chain Compounds and Cyclic Compounds, along with their types:


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🧪 CLASSIFICATION OF ORGANIC COMPOUNDS

Organic compounds are primarily classified based on the arrangement of their carbon atoms into:


1️⃣ OPEN CHAIN COMPOUNDS (Acyclic Compounds)

✅ These compounds contain straight or branched chains of carbon atoms.
❌ They do not form any rings.

🔹 Examples:

  • Straight Chain:

    • Methane: CH₄

    • Propane: CH₃–CH₂–CH₃

  • Branched Chain:

    • Isobutane:
      CH₃–CH(CH₃)–CH₃


2️⃣ CYCLIC COMPOUNDS (Closed Chain Compounds)

✅ These contain carbon atoms arranged in rings.
They are further classified into two major types:


🔄 A. Homocyclic (Carbocyclic) Compounds

Ring contains only carbon atoms.

➤ (i) Alicyclic Compounds

  • Resemble aliphatic compounds in behavior.

  • Ring of carbon atoms only, non-aromatic.

📘 Examples:

  • Cyclopropane (C₃H₆)

  • Cyclobutane (C₄H₈)

➤ (ii) Aromatic Compounds

  • Contain conjugated π-electrons in ring.

  • Follow Hückel’s rule: (4n + 2) π electrons.

📘 Examples:

  • Benzene (C₆H₆)

  • Naphthalene (C₁₀H₈)


🔄 B. Heterocyclic Compounds

Ring contains carbon atoms + other atoms (like O, N, S)

📘 Examples:

  • Furan (O in ring)

  • Pyridine (N in ring)

  • Thiophene (S in ring)


🔍 Summary Chart:

Type Sub-type Key Feature Example
Open Chain Acyclic Straight or branched chains Butane
Cyclic Alicyclic Ring of C atoms, non-aromatic Cyclopentane
Aromatic Ring with conjugated π system Benzene
Heterocyclic Ring with C + other atoms (O, N, S) Furan, Pyridine

📚 Tips to Remember:

  • “Alicyclic” = Aliphatic + Cyclic

  • “Aromatic” = Smells + Special stability (resonance)

  • “Heterocyclic” = Hetero (different) atoms in ring


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CLASSIFICATION OF ORGANIC COMPOUND – OPEN CHAIN COMPOUND – CYCLIC COMPOUND AND ITS TYPE.

Organic chemistry – sOme Basic PrinciPles and Techniques

Nomenclature of Organic Compounds



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