Physical Chemistry – The Solid State-Concept of Crystals, Crystallography, Inter facial – part-4.

Physical Chemistry – The Solid State-Concept of Crystals, Crystallography, Inter facial – part-4.



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Here is a well-organized explanation of Physical Chemistry – The Solid State (Part-4), covering concepts of Crystals, Crystallography, and Interfacial Angles. This is perfect for Class 12 or undergraduate students:


Contents [hide]

🧪 Physical Chemistry – The Solid State

📘 Part-4: Crystals, Crystallography, and Interfacial Angle


💠 What is a Crystal?

A crystal is a solid in which the atoms, ions, or molecules are arranged in a definite and repeating pattern in three dimensions.

Example: Salt (NaCl), Quartz (SiO₂), Diamond, Sugar


📐 Crystallography – The Science of Crystals

Crystallography is the branch of science that studies the geometry, structure, and properties of crystals.

🔍 Focus Areas:

  • Shape and size of crystals

  • Unit cell and lattice structure

  • Symmetry and crystal systems

  • Interfacial angles (important concept below)


📏 Interfacial Angle – Definition

🔺 Interfacial angle is the angle between any two adjacent faces of a crystal.

📌 Key Fact:

The interfacial angle is constant for all crystals of the same substance, regardless of size or shape.

This is called Steno’s Law (Law of Constancy of Interfacial Angles).


🧱 Types of Crystalline Solids (Recap):

Type Particles Involved Bond Type Examples
Ionic Crystals Ions Electrostatic NaCl, KCl
Covalent Crystals Atoms Covalent bonds Diamond, SiO₂
Molecular Crystals Molecules Van der Waals, H-bond Ice, CO₂
Metallic Crystals Metal atoms Metallic bonding Fe, Cu, Zn

🧬 Crystalline vs Amorphous Solids

Feature Crystalline Solid Amorphous Solid
Particle Arrangement Regular, repeating Irregular, random
Sharp melting point Yes No
Long-range order Yes No
Example Quartz, NaCl, Diamond Glass, Plastic, Wax

🧊 Crystal Lattice and Unit Cell (Intro for Next Part)

  • Crystal Lattice: 3D arrangement of particles.

  • Unit Cell: The smallest repeating unit in a crystal lattice.

You’ll learn more about:

  • Types of unit cells (Simple, BCC, FCC)

  • Bravais lattices

  • Edge length, radius relation, etc. in the next parts.


📌 Summary:

Crystals have a regular arrangement of particles and constant interfacial angles, which is studied under Crystallography. This regularity gives solids their specific shapes, properties, and behavior.


Would you like:

  • A visual diagram of crystal structure?

  • A video script or Hindi translation?

  • Or numerical problems on interfacial angle and unit cells?

Let me know how you’d like to continue to Part 5!

Physical Chemistry – The Solid State-Concept of Crystals, Crystallography, Inter facial – part-4.

Solid state Notes.pdf

Laws of Crystallography and Crystal System

B.Sc. Sem. II,Chemistry,P.IV,5.Solid State



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